1000-05-1Relevant articles and documents
Sakiyama,Okawara
, p. 473,476 (1964)
Engelhardt
, p. 243,245 (1968)
Copper-catalyzed formic acid synthesis from CO2 with hydrosilanes and H2O
Motokura, Ken,Kashiwame, Daiki,Miyaji, Akimitsu,Baba, Toshihide
experimental part, p. 2642 - 2645 (2012/08/13)
A copper-catalyzed formic acid synthesis from CO2 with hydrosilanes has been accomplished. The Cu(OAc)2?H 2O-1,2-bis(diphenylphosphino)benzene system is highly effective for the formic acid synthesis under 1 atm of CO2. The TON value approached 8100 in 6 h. The reaction pathway was revealed by in situ NMR analysis and isotopic experiments.
Composition for separating mixtures
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Page/Page column 17, (2008/06/13)
Therefore, there is provided herein in one specific embodiment a composition comprising: a) at least one silicone surfactant, and where silicone of silicone surfactant (a) has the general structure of: [in-line-formulae]Ma1Mb2Dc1Dd2Te1Tf2Qg; [/in-line-formulae][in-line-formulae]and, [/in-line-formulae][in-line-formulae]2≦(a+b+c+d+e+f+g)≦100; and, [/in-line-formulae] b) a mixture comprising an aqueous phase, a solid filler phase and optionally an oil phase that is substantially insoluble in said aqueous phase.