1002353-06-1

Basic information

• Product Name: 6-benzyl 1-methyl 2-methylenehexanedioate
• Synonyms: 6-benzyl 1-methyl 2-methylenehexanedioate
• CAS NO: 1002353-06-1
• Molecular Weight: 262.306
• Mol File: 1002353-06-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-benzyl 1-methyl 2-methylenehexanedioate(CAS DataBase Reference)
• NIST Chemistry Reference: 6-benzyl 1-methyl 2-methylenehexanedioate(1002353-06-1)
• EPA Substance Registry System: 6-benzyl 1-methyl 2-methylenehexanedioate(1002353-06-1)

Safety Data

• Hazardous Substances Data: 1002353-06-1(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 100-51-6 benzyl alcohol 
• 126430-46-4 benzyl 4-bromobutanoate 

Downstream Products

• 10386-81-9 methyl 1-benzyl-2-oxocyclopentanecarboxylate 

Relevant articles and documents

A new method for constructing quaternary carbon centres: Tandem rhodium-catalysed 1,4-addition/intramolecular cyclisation

The efficient tandem rhodium-catalysed 1,4-addition/cyclisation of 1,1′-alkenes using arylzinc chlorides is described. The simple one-step synthesis of substituted cyclopentanone and cyclohexanone derivatives is performed from acyclic precursors using relatively low catalyst loadings under mild conditions. A new quaternary carbon centre is created during the cyclisation step.