10035-06-0 Usage
Description
Bismuth nitrate pentahydrate is a non-toxic, inexpensive, easy to handle, and air-insensitive reagent, commonly used in organic synthesis with a wide range of applications. It is the bismuth salt form of nitrate, usually existing in pentahydrate form, and is known for its various uses in different industries.
Uses
Used in Organic Synthesis:
Bismuth nitrate pentahydrate is used as a reagent for a variety of applications in organic synthesis, including the conversion of thiocarbonyls to their carbonyl compounds and the oxidative deprotection of dithioacetals.
Used in Pharmaceutical Industry:
Bismuth nitrate pentahydrate is used as a catalyst in the chemo-selective synthesis of acylals from aromatic aldehydes, one-pot synthesis of alpha-amino phosphates, and pharmaceutically functionalized piperidine derivatives.
Used in Cosmetics, Batteries, Paints, and Pigment Plastics Manufacturing:
Bismuth nitrate pentahydrate is used as an additive in the manufacturing of cosmetics, batteries, paints, and pigment plastics.
Used in Photocatalyst Preparation:
Bismuth nitrate pentahydrate acts as a precursor in the preparation of photocatalysts.
Used in Luminous Paints and Bismuth Salts Preparation:
Bismuth nitrate pentahydrate is used in the preparation of luminous paints and bismuth salts.
Used as an Oxidant:
Bismuth nitrate pentahydrate is an excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines and serves as a reagent for selective oxidation of sulfides to sulfoxides.
Used in the Preparation of Dragendorff Reagent and as a TLC Stain:
Bismuth nitrate pentahydrate is involved in the preparation of Dragendorff reagent and is used as a thin-layer chromatography (TLC) stain.
Physical Properties:
Bismuth nitrate pentahydrate is characterized by its lustrous triclinic crystals, acid taste, hygroscopic nature, density of 2.83 g/cm3, decomposition at 75°C, slow reaction with water, solubility in acids and acetone, and insolubility in alcohol.
Chemical Properties:
Bismuth nitrate pentahydrate is a white crystalline compound with various applications in different industries, making it a versatile and valuable reagent in organic synthesis and other fields.
Chemical Synthesis
Bismuth(III) nitrate pentahydrate may be used in the following processes:
Conversion of thioamides and thioureas to their oxo derivatives.
Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions.
Synthesize coumarins by Pechmann condensation under solvent free conditions.
As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics.
As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrobenzenes under microwave irradiation.
As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives.
Synthesis of glycosides by Fischer glycosylation of unprotected sugars.
Synthesis of bismuth oxide (Bi2O3) nanoparticles.
Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines.
Selective oxidation of sufides to sulfoxides.
Preparation
Bismuth nitrate pentahydrate can be obtained by dissolving metallic bismuth granules in nitric acid, or by pouring molten metallic bismuth into an acid solution while stirring.
Preparation
Bismuth nitrate is prepared by dissolving bismuth in concentrated nitric acid, followed by evaporation and crystallization .
Sources
https://en.wikipedia.org/wiki/Bismuth(III)_nitrate
Bhattacharya, Asish K., and T. Kaur. ?Cheminform 38.30(2007):0745-0748.
Aggen, David H., et al. Tetrahedron 35.31(2004):3675-3679.
Brahmachari, Goutam, and S. Das. Cheminform 43.28(2012):1479-1484.
Srivastava, Neeta, S. K. Dasgupta, and B. K. Banik. Tetrahedron Letters 34.17(2003):1191-1193.
Banik, Bimal K., I. Garcia, and F. R. Morales. Cheminform 38.33(2007):no-no.
Srivastava, N, and B. K. Banik. Cheminform 68.6(2003):2109-14.
https://www.sigmaaldrich.com/catalog/product/aldrich/254150?lang=en®ion=US
https://www.webmd.com/vitamins/ai/ingredientmono-1502/bismuth
Check Digit Verification of cas no
The CAS Registry Mumber 10035-06-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,0,3 and 5 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 10035-06:
(7*1)+(6*0)+(5*0)+(4*3)+(3*5)+(2*0)+(1*6)=40
40 % 10 = 0
So 10035-06-0 is a valid CAS Registry Number.
InChI:InChI=1/Bi.NO3.5H2O/c;2-1(3)4;;;;;/h;;5*1H2/q+3;-1;;;;;
