10042-59-8Relevant articles and documents
Guerbet reaction of primary alcohols leading to β-alkylated dimer alcohols catalyzed by iridium complexes
Matsu-Ura, Toyomi,Sakaguchi, Satoshi,Obora, Yasushi,Ishii, Yasutaka
, p. 8306 - 8308 (2006)
[IrCl(cod)]2 and [Cp*IrCl2]2 complexes catalyzed efficiently the Guerbet reaction of primary alcohols to β-alkylated dimer alcohols in good yields. For instance, the reaction of 1-butanol in the presence of [Cp*IrCl2]2 (1 mol %), t-BuOK (40 mol %), and 1,7-octadiene (10 mol %) produced 2-ethyl-1-hexanol in 93% yield. Various primary alcohols undergo the Guerbet reaction under the influence of Ir complexes to give the corresponding dimer alcohols in good yields. This method provides an alternative direct route to β-alkylated primary alcohols which are prepared by aldol condensation of aldehydes followed by hydrogenation.
Effect of second metal component on the reduction property and catalytic performance of NiO-MOx/Nb2O5-TiO2 for direct synthesis of 2-propylheptanol from n-valeraldehyde
An, Hualiang,Wang, Yanji,Zhao, Lili,Zhao, Xinqiang
, (2021)
In order to improve the catalytic performance of NiO/Nb2O5-TiO2, several kinds of the second metal oxide component MOx (M = Pd, Co, Ir or Rh) were separately introduced and their effects on the reduction propert
Watanabe et al.
, p. 3369 (1978)
READILY BIODEGRADABLE ALKOXYLATE MIXTURES
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Paragraph 0040-0043, (2021/05/14)
A mixture of octanols, nonanols and decanols is useful for the preparation of alkoxylates, which alkoxylates may be used as surfactants, which surfactants have surprisingly good biodegradability.