1007131-02-3

Basic information

• Product Name: C₁₇H₂₂O
• CAS NO: 1007131-02-3
• Molecular Weight: 242.361
• Mol File: 1007131-02-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₇H₂₂O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₇H₂₂O(1007131-02-3)
• EPA Substance Registry System: C₁₇H₂₂O(1007131-02-3)

Safety Data

• Hazardous Substances Data: 1007131-02-3(Hazardous Substances Data)

Upstream product

• 25910-98-9 2-cyclohexyl-2-methyloxirane 
• 33440-88-9 silver phenylacetylide 

Relevant articles and documents

Zirconium-promoted epoxide rearrangement-alkynylation sequence

(Chemical Equation Presented) Additions of terminal alkynes to electrophiles are important transformations in organic chemistry. Generally, activated terminal alkynes react with epoxides in an SN2 fashion to form homopropargylic alcohols. We have developed a new synthetic method to form propargylic alcohols from epoxides and terminal alkynes via 1,2-shifts. This method involves cationic zirconium acetylides as both the activator of epoxides and nucleophiles. Due to the mild conditions to pre-activate alkynes with silver nitrate, this synthetic method is useful for both electron-rich and electron-deficient alkynes with other acid- and base-sensitive functional groups.