101089-24-1

Basic information

• Product Name: 2-acetyl-3-oxo-5-phenyl-valeric acid ethyl ester
• Synonyms: 2-acetyl-3-oxo-5-phenyl-valeric acid ethyl ester
• CAS NO: 101089-24-1
• Molecular Weight: 262.306
• Mol File: 101089-24-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-acetyl-3-oxo-5-phenyl-valeric acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-acetyl-3-oxo-5-phenyl-valeric acid ethyl ester(101089-24-1)
• EPA Substance Registry System: 2-acetyl-3-oxo-5-phenyl-valeric acid ethyl ester(101089-24-1)

Safety Data

• Hazardous Substances Data: 101089-24-1(Hazardous Substances Data)

Upstream product

• 645-45-4 hydrocinnamic acid chloride 
• 1007476-32-5 sodium ethyl acetylacetate enolate 
• 141-97-9 ethyl acetoacetate 
• 76352-65-3 ethyl (E)-2-acetyl-3-oxo-5-phenylpent-4-enoate 

Downstream Products

• 17071-29-3 ethyl 3-oxo-5-phenylpentanoate 
• 30414-58-5 methyl 3-oxo-5-phenylpentanoate 
• 182682-12-8 3-methyl-1-phenyl-4-(3-phenylpropionyl)-1,2-dihydropyrazol-5-one 

Relevant articles and documents

An alternative isoxazole route to α-alkoxycarbonyl-β-diketones

Cycloaddition of oxygen-functionalized nitrite oxides to the enamine from ethyl acetoacetate produces 4-ethoxycarbonyl-5-methylisoxazoles carrying a 3-tetrahydropyranyloxymethyl, 3-diethoxymethyl or 3-ethoxycarbonyl substituent; the 3-formylisoxazole is prepared from the former two and condensed in situ with phosphoranes to give 3-alkenylisoxazoles that are cleaved by hexacarbonylmolybdenum or hydrogenolysis to afford α-alkoxycarbonyl-β-diketones.