101273-46-5Relevant articles and documents
Orange-Red Phosphorescent Iridium(III) Complexes Bearing Bisphosphine Ligands: Synthesis, Photophysical and Electrochemical Properties, and DFT Calculations
Li, Gao-Nan,Dou, Shao-Bin,Zheng, Tao,Chen, Xiao-Qing,Yang, Xiao-Han,Wang, Shuang,Sun, Wei,Chen, Guang-Ying,Mo, Zheng-Rong,Niu, Zhi-Gang
, p. 78 - 86 (2018)
Nine new phosphorus-coordinated iridium(III) complexes of the form [Ir(C^N)2(P^P)]PF6, [Ir(F-piq)2(xantphos)]PF6 (1), [Ir(F-piq)2(binap)]PF6 (2), [Ir(F-piq)2/sub
Copper-catalyzed cross-coupling of aryl-, primary alkyl-, and secondary alkylboranes with heteroaryl bromides
Bergmann, Allison M.,Oldham, Adam M.,You, Wei,Brown, M. Kevin
, p. 5381 - 5384 (2018)
A method for the Cu-catalyzed cross-coupling of both aryl and alkylboranes with aryl bromides is described. The method employs an inexpensive Cu-catalyst and functions for a variety of heterocyclic as well as electron deficient aryl bromides. In addition, aryl iodides of varying substitution patterns and electronic properties work well.
Synthesis of a heptaarylisoquinoline: Unusual disconnection for constructing isoquinoline frameworks
Asako, Takashi,Suzuki, Shin,Itami, Kenichiro,Muto, Kei,Yamaguchi, Junichiro
, p. 968 - 970 (2018)
In a novel disconnection of isoquinoline ring synthesis at the C7C8/C4aC8a bonds, these bonds can be formed by a [4+2] cycloaddition between thiophene S,S-dioxide and alkynes. With a subsequent CH arylation of the resulting hexaarylisoquinoline at the C3 position, the synthesis of a fully substituted isoquinoline has been achieved.
Phase-selective modulation of TiO2 for visible light-driven C–H arylation: Tuning of absorption and adsorptivity
Bak, Sora,Lee, Sae Mi,Hwang, Hee Min,Lee, Hyoyoung
, p. 71 - 76 (2019/05/08)
To understand and modify TiO2 for organic photoreaction, two points are important: improving light absorption and retaining adsorption sites for organic reagents. Herein, we tuning the absorption and adsorption of TiO2 by introducing
