102319-30-2

Basic information

• Product Name: methyl-(1,1,2-triphenyl-ethyl)-ether
• Synonyms: methyl-(1,1,2-triphenyl-ethyl)-ether
• CAS NO: 102319-30-2
• Molecular Weight: 288.389
• Mol File: 102319-30-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl-(1,1,2-triphenyl-ethyl)-ether(CAS DataBase Reference)
• NIST Chemistry Reference: methyl-(1,1,2-triphenyl-ethyl)-ether(102319-30-2)
• EPA Substance Registry System: methyl-(1,1,2-triphenyl-ethyl)-ether(102319-30-2)

Safety Data

• Hazardous Substances Data: 102319-30-2(Hazardous Substances Data)

Upstream product

• 1016-09-7 benzhydryl methyl ether 
• 100-44-7 benzyl chloride 
• 67-56-1 methanol 
• 900-91-4 3,3,3-triphenylpropionic acid 
• 7664-93-9 sulfuric acid 
• 4428-13-1 1,1,2-Triphenylethanol 
• 808-85-5 toluene-4-sulfonic acid 2,2,2-triphenyl-ethyl ester 

Downstream Products

• 16876-18-9 1,2,2-triphenylpropane 
• 6393-05-1 1,2,2,4-tetraphenyl-butane 

Relevant articles and documents

Electrochemical oxidative decarboxylation and 1,2-aryl migration towards the synthesis of 1,2-diaryl ethers

Carboxylic acid compounds are important chemicals and are widely present in various natural products. They are not only nucleophiles, but also radical precursors. Classic transition-metal-catalyzed and photochemical decarboxylation have shown their excellent site selectivity in radical chemistry. However, electrochemical decarboxylation with a long history hasn't got enough attention in recent years. In this work, the electrochemical oxidative decarboxylation and 1,2-aryl migration of 3,3-diarylpropionic acids have been introduced to construct C-O bonds with alcohols. Remarkably, this transformation can proceed smoothly without metal catalysts and external oxidants.