102448-99-7

Basic information

• Product Name: N-(2-(cyclohex-1-en-1-yl)ethyl)-1,1-diphenylmethanimine
• Synonyms: N-(2-(cyclohex-1-en-1-yl)ethyl)-1,1-diphenylmethanimine
• CAS NO: 102448-99-7
• Molecular Weight: 289.42
• Mol File: 102448-99-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(2-(cyclohex-1-en-1-yl)ethyl)-1,1-diphenylmethanimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-(cyclohex-1-en-1-yl)ethyl)-1,1-diphenylmethanimine(102448-99-7)
• EPA Substance Registry System: N-(2-(cyclohex-1-en-1-yl)ethyl)-1,1-diphenylmethanimine(102448-99-7)

Safety Data

• Hazardous Substances Data: 102448-99-7(Hazardous Substances Data)

Upstream product

• 119-61-9 benzophenone 
• 3399-73-3 2-(1-cyclohexenyl)ethylamine 

Downstream Products

• 101871-19-6 (2-cyclohex-1-enyl-ethyl)-methyl-amine 
• 38969-65-2 1-(p-methoxybenzyl)-2-methyl-1,2,3,4,5,6,7,8-octahydroisoquinoline 
• 118646-96-1 (2-cyclohex-1-enyl-ethyl)-(4-methoxy-styryl)-methyl-amine 
• 118646-97-2 1-(4-methoxy-benzyl)-2-methyl-1,2,3,4,6,7,8,8a-octahydro-isoquinoline 
• 46878-16-4 1-benzyl-2-methyl-1,2,3,4,5,6,7,8-octahydro-isoquinoline 
• 872788-53-9 1-benzyl-2-methyl-octahydro-isoquinolin-4a-ol 

Relevant articles and documents

Visible-Light-Induced Cycloaddition of α-Ketoacylsilanes with Imines: Facile Access to β-Lactams

We report the synthesis of β-lactams from α-ketoacylsilanes and imines, which proceeds via a formal [2+2] photochemical cycloaddition with in situ generation of siloxyketene. This mild and operationally simple reaction proceeds in an atom-economic fashion with broad substrate scope, including aldimines, ketimines, hydrazones, and fused nitrogen heterocycles, affording a variety of important β-lactams with satisfactory diastereoselectivities in most cases. This reaction also features good functional-group tolerance, facile scalability and product diversification. Experimental and computational studies suggest that α-ketoacylsilanes can serve as photochemical precursors by engaging in a 1,3 silicon shift to the distal carbonyl group.