102519-81-3

Basic information

• Product Name: 2,6-Di-tert-butyl-4-(2-methyl-1-phenyl-propenyl)-phenol
• Synonyms: 2,6-Di-tert-butyl-4-(2-methyl-1-phenyl-propenyl)-phenol
• CAS NO: 102519-81-3
• Molecular Weight: 336.517
• Mol File: 102519-81-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,6-Di-tert-butyl-4-(2-methyl-1-phenyl-propenyl)-phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-Di-tert-butyl-4-(2-methyl-1-phenyl-propenyl)-phenol(102519-81-3)
• EPA Substance Registry System: 2,6-Di-tert-butyl-4-(2-methyl-1-phenyl-propenyl)-phenol(102519-81-3)

Safety Data

• Hazardous Substances Data: 102519-81-3(Hazardous Substances Data)

Upstream product

• 102519-80-2 2,6-Di-tert-butyl-4-(1-phenyl-vinyl)-phenol 
• 7175-89-5 3,5-di-t-butyl-4-hydroxybenzophenone 
• 611-70-1 phenyl isopropyl ketone 
• 1516-96-7 4-bromo-2,6-di-tert-butylanisole 

Downstream Products

• 7175-89-5 3,5-di-t-butyl-4-hydroxybenzophenone 
• 102519-83-5 2,6-Di-tert-butyl-4-(2-hydroperoxy-2-methyl-1-phenyl-propylidene)-cyclohexa-2,5-dienone 
• 102535-11-5 2,4-Di-tert-butyl-2-hydroxy-6-(2-methyl-1-phenyl-propenyl)-7-oxa-bicyclo[4.1.0]hept-4-en-3-one 

Relevant articles and documents

Attempted Synthesis of a Stable, Quintet, Tetraphenoxyl Tetraradical: Facile Rearrangement of a Substituted Bicyclobutane

The preparation of tetraphenol 3 and its attempted oxidation to tetraradical 2 are described. Tetraphenoxyl 2 was envisioned as a more stable analog of the previously reported, quintet tetraradical 1. However, EPR studies on 3 and model compounds and crystallographic characterization of the product from oxidation of 3 suggest that 2 is not a viable target. Apparently, 2 or an intermediate in the multistep oxidation path leading to it undergoes a ring closure to a bicyclobutane. The bicyclobutane, in turn, undergoes a surprisingly facile rearrangement to the analogous butadiene structure.