102607-00-1

Basic information

• Product Name: Ethanethioic acid, S-[(4-methoxyphenyl)methyl] ester
• CAS NO: 102607-00-1
• Molecular Formula: C10H12O2S
• Molecular Weight: 196.27
• Mol File: 102607-00-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Ethanethioic acid, S-[(4-methoxyphenyl)methyl] ester(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanethioic acid, S-[(4-methoxyphenyl)methyl] ester(102607-00-1)
• EPA Substance Registry System: Ethanethioic acid, S-[(4-methoxyphenyl)methyl] ester(102607-00-1)

Safety Data

• Hazardous Substances Data: 102607-00-1(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 2746-25-0 p-Methoxybenzyl bromide 
• 10387-40-3 potassium thioacetate 
• 6258-60-2 p-methoxybenzylmercaptan 
• 54879-64-0 N-[(4-methoxyphenyl)methyl]-4-methylbenzenesulfonamide 
• 507-09-5 tiolacetic acid 
• 105-13-5 4-Methoxybenzyl alcohol 

Downstream Products

• 824-94-2 p-methoxybenzyl chloride 
• 1314028-62-0 methyl 4-[(4-methoxybenzyl)sulfanyl]benzoate 
• 6258-60-2 p-methoxybenzylmercaptan 

Relevant articles and documents

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Suitable for UV - LED light curing of the naphthalimide aryl benzyl [...] photoinitiator and preparation method and application

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Selective benzylic and allylic alkylation of protic nucleophiles with sulfonamides through double Lewis acid catalyzed cleavage of sp3 carbon-nitrogen bonds

The acid-catalyzed benzylic and allylic alkylation of protic nucleophiles is fundamentally important for the formation of carbon-carbon and carbon-heteroatom bonds, and it is a formidable challenge for benzylic and allylic amine derivatives to be used as the alkylating agents. Herein we report a highly efficient benzylic and allylic alkylation of protic carbon and sulfur nucleophiles with sulfonamides through double Lewis acid catalyzed cleavage of sp3 carbon-nitrogen bonds at room temperature. In the presence of a catalytic amount of inexpensive ZnCl2-TMSCl (TMSCl: chlorotrimethylsilane), 1,3-diketones, β-keto esters, β-keto amides, malononitrile, aromatic compounds, thiols, and thioacetic acid can couple with a broad range of tosylactivated benzylic and allylic amines to give diversely functionalized products in good to excellent yields and with high regioselectivity. Furthermore, the cross-coupling reaction of 1,3-dicarbonyl compounds with benzylic propargylic amine derivatives has been successfully applied to the one-step synthesis of polysubstituted furans and benzofurans.