102676-97-1

Basic information

• Product Name: 1-(2,6,6-trimethyl-1,3-cyclohexadienyl)ethanol
• Synonyms: 1-(2,6,6-trimethyl-1,3-cyclohexadienyl)ethanol
• CAS NO: 102676-97-1
• Molecular Weight: 166.263
• Mol File: 102676-97-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(2,6,6-trimethyl-1,3-cyclohexadienyl)ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2,6,6-trimethyl-1,3-cyclohexadienyl)ethanol(102676-97-1)
• EPA Substance Registry System: 1-(2,6,6-trimethyl-1,3-cyclohexadienyl)ethanol(102676-97-1)

Safety Data

• Hazardous Substances Data: 102676-97-1(Hazardous Substances Data)

Upstream product

• 116-26-7 safranal 
• 917-54-4 methyllithium 

Downstream Products

• 19620-37-2 (+/-)-4-hydroxy-2,6,6-trimethyl-2-cyclohexenone 
• 41436-46-8 2,6,6-trimethyl-cyclohexa-1,3-dien-1-yl methyl ketone 
• 54200-67-8 2',3',6'-trimethylacetophenone 

Relevant articles and documents

Photochemical Reactions. 145th Communication. Carbonyl vs. Epoxyketone Photochemistry: Photolysis of 1,2;3,4-Diepoxy-2,6,6-trimethyl-1-cyclohexyl Methyl Ketone

The synthesis and photolysis of the title compound 3 is described.Irradiation (λ > 280 nm, MeCN) of the di-epoxyketone 3 leads predominantly to γ-H abstraction.Cyclization furnishes the cyclobutanols 22-24, while cleavage gives compound 25, presumably via the allene-oxide intermediate 36.Further, products 27 and 28 are formed by Norrish fragmentation and by initial cleavage of the C(α)-O bond of the oxirane, respectively.The structures of the products 22-25, 27, and 28 were assigned on the basis of the spectral data of the photolysis products of the 13C-labelled diepoxyketone -3 and by X-ray analysis of the compounds 24 and 35, the latter being the p-nitrobenzoate of 22.