1027537-24-1

Basic information

• Product Name: (4-tetradecylphenyl)[2-(trimethylsilyl)phenyl]iodonium triflate
• Synonyms: (4-tetradecylphenyl)[2-(trimethylsilyl)phenyl]iodonium triflate
• CAS NO: 1027537-24-1
• Molecular Weight: 698.745
• Mol File: 1027537-24-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4-tetradecylphenyl)[2-(trimethylsilyl)phenyl]iodonium triflate(CAS DataBase Reference)
• NIST Chemistry Reference: (4-tetradecylphenyl)[2-(trimethylsilyl)phenyl]iodonium triflate(1027537-24-1)
• EPA Substance Registry System: (4-tetradecylphenyl)[2-(trimethylsilyl)phenyl]iodonium triflate(1027537-24-1)

Safety Data

• Hazardous Substances Data: 1027537-24-1(Hazardous Substances Data)

Upstream product

• 181523-24-0 1-iodo-4-tetradecylbenzene 
• 91323-12-5 4-tetradecylaniline 
• 1493-13-6 trifluorormethanesulfonic acid 
• 17151-09-6 1,2-bis(trimethylsilyl)benzene 
• 536985-44-1 1-(diacetoxyiodo)-4-tetradecylbenzene 

Downstream Products

• 751-38-2 1,2,3,4-tetraphenylnaphthalene 
• 181523-24-0 1-iodo-4-tetradecylbenzene 
• 573-57-9 1,4-dihydronaphthalene-1,4-epoxide 

Relevant articles and documents

Improved solubility of hypervalent iodine-benzyne precursors: Synthesis and reaction of (phenyl)[2-(trimethylsilyl)phenyl]iodonium salts bearing long alkyl chains

Synthesis of new long-chained hypervalent iodine-benzyne precursors, (4-dodecylphenyl)[2-(trimethylsilyl)phenyl]iodonium triflate and the tetradecyl derivative, is described. The benzyne precursors dissolve even in organic solvents of low polarity such as diethyl ether, THF, cyclopentyl methyl ether, benzene, and toluene. The trapping reactions with furan and tetraphenylcy-clopentadienone in the above solvent give the benzyne adducts in high yields without any loss of high reactivity of hypervalent iodine-benzyne precursors.