1033618-36-8

Basic information

• Product Name: (1S,2S)-N,N-bis(2-isopropoxyphenyl)-1,2-diphenylethane-1,2-diamine
• Synonyms: (1S,2S)-N,N-bis(2-isopropoxyphenyl)-1,2-diphenylethane-1,2-diamine
• CAS NO: 1033618-36-8
• Molecular Weight: 480.65
• Mol File: 1033618-36-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2S)-N,N-bis(2-isopropoxyphenyl)-1,2-diphenylethane-1,2-diamine(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S)-N,N-bis(2-isopropoxyphenyl)-1,2-diphenylethane-1,2-diamine(1033618-36-8)
• EPA Substance Registry System: (1S,2S)-N,N-bis(2-isopropoxyphenyl)-1,2-diphenylethane-1,2-diamine(1033618-36-8)

Safety Data

• Hazardous Substances Data: 1033618-36-8(Hazardous Substances Data)

Upstream product

• 701-07-5 1-bromo-2-isopropoxybenzene 
• 29841-69-8 (S,S)-1,2-diphenyl-1,2-diaminoethane 

Downstream Products

• 1033618-51-7 (4S,5S)-1,3-bis(2-isopropoxyphenyl)-4,5-diphenyl-4,5-dihydro-1H-imidazol-3-ium tetrafluoroborate 

Relevant articles and documents

C2 symmetric chiral NHC ligand for asymmetric quaternary carbon constructing copper-catalyzed conjugate addition of Grignard reagents to 3-substituted cyclohexenones

(Chemical Equation Presented) The asymmetric construction of quaternary carbon centers by conjugate addition of Grignard reagents to 3-methyl- and 3-ethylcyclohexenones was realized in a maximum enantioselectivity of 80% by using a C2 symmetric chiral N-heterocyclic carbene (NHC)-copper catalyst, generated from (4S,5S)-1,3-bis(2-methoxyphenyl)-4,5-diphenyl-4,5- dihydro-1H-imidazol-3-ium tetrafluoroborate and copper(II) triflate. The stereostructures of the NHC-Au complexes were analyzed by X-ray crystallography, which rationalized the good stereocontrolling ability of N-aryl NHCs.