103441-80-1

Basic information

• Product Name: 2-oxo-2-(pyridin-2-yl)ethyl acetate
• CAS NO: 103441-80-1
• Molecular Weight: 179.175
• Mol File: 103441-80-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-oxo-2-(pyridin-2-yl)ethyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-oxo-2-(pyridin-2-yl)ethyl acetate(103441-80-1)
• EPA Substance Registry System: 2-oxo-2-(pyridin-2-yl)ethyl acetate(103441-80-1)

Safety Data

• Hazardous Substances Data: 103441-80-1(Hazardous Substances Data)

Upstream product

• 95836-52-5 2-(α-hydroxyacetyl)pyridine 
• 108-24-7 acetic anhydride 
• 188897-71-4 N-(1-(pyridin-2-yl)vinyl)acetamide 
• 127-09-3 sodium acetate 
• 17570-98-8 2-(bromoacetyl)pyridine hydrobromide 
• 115933-92-1 2-(1-acetoxyvinyl)pyridine 1-oxide 
• 2457-50-3 2-acetylpyridine N-oxide 
• 1122-62-9 2-acetylpyridine 
• 115933-93-2 2-(1,2-diacetoxyvinyl)pyridine 
• 127-08-2 potassium acetate 

Downstream Products

• 95836-52-5 2-(α-hydroxyacetyl)pyridine 

Relevant articles and documents

Novel and efficient transformation of enamides into α-acyloxy ketones via an acyl intramolecular migration process

Hydrogen peroxide and anhydride mediated transformation of enamides to afford substituted α-acyloxy ketones is described. This transition-metal-free cascade reaction has a broad substrate scope and high efficiency. The acyl intramolecular migration procedure successfully achieved this acyloxylation process under mild conditions and increased the atom efficiency.

REACTIONS OF 2-ACYLPYRIDINE 1-OXIDES WITH ACID ANHYDRIDES

Treatment of 2-acetyl- and 2-propionyl-pyridine 1-oxides (1a and 1b) with hot acetic, propionic and benzoic anhydrides initially gives the respective enol acylates (A), which further undergo deoxygenative β-acyloxylation to give enediol diacylates (E) and