103913-29-7Relevant articles and documents
Palladium-catalyzed amination of aryl sulfides with aliphatic amines
Gao, Ke,Yorimitsu, Hideki,Osuka, Atsuhiro
, p. 2678 - 2682 (2015)
Conditions for the palladium-NHC-catalyzed amination of aryl sulfides with aliphatic as well as aromatic amines were established. The KHMDS-mediated amination of heteroaryl sulfides could proceed without palladium. Based on the distinct difference in reactivity of C-Br and C-S bonds, a sequential amination of bromothioanisole can take place to install two different alkylamino groups onto the aromatic ring in one pot. A palladium-NHC precatalyst shows high efficiency for C-S bond cleavage for the amination of aryl sulfides with aliphatic amines or aromatic amines.
N’-acyl-N-methylphenylenediamine as a novel proximity labeling agent for signal amplification in immunohistochemistry
Sato, Shinichi,Yoshida, Masaki,Hatano, Kensuke,Matsumura, Masaki,Nakamura, Hiroyuki
, p. 1110 - 1118 (2019/02/09)
We synthesized novel phenylenediamine derivatives and evaluated them as labeling agents to label proteins in close proximity to a single electron transfer catalyst. We found that N’-acyl-N-methylphenylenediamine labels tyrosine effectively in a model expe
Rapid and convenient synthesis of N-arylmorpholines under microwave irradiation
Li, Hong Bo,Liang, Wu,Ma, Chang Peng,Kai, Yong Mao,Li, Lei,Zhang, Yong Gang
, p. 995 - 998 (2013/08/23)
A series of N-arylmorpholines 1a-1n was obtained by cyclocondensation of arylamines and diethylene glycol dimesylate under microwave irradiation in an aqueous potassium carbonate medium. The reaction is rapid and convenient, and a variety of functional groups are tolerated in the process.