104113-84-0

Basic information

• Product Name: Phenol, 4-[(dimethylamino)methyl]-2-methoxy-6-methyl-
• CAS NO: 104113-84-0
• Molecular Formula: C11H17NO2
• Molecular Weight: 195.261
• Mol File: 104113-84-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phenol, 4-[(dimethylamino)methyl]-2-methoxy-6-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 4-[(dimethylamino)methyl]-2-methoxy-6-methyl-(104113-84-0)
• EPA Substance Registry System: Phenol, 4-[(dimethylamino)methyl]-2-methoxy-6-methyl-(104113-84-0)

Safety Data

• Hazardous Substances Data: 104113-84-0(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 2896-67-5 2-methyl-6-methoxyphenol 
• 124-40-3 dimethyl amine 
• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 
• 4383-05-5 2-hydroxy-3-methoxybenzyl alcohol 

Downstream Products

• 116733-76-7 [2-(1,5-Dimethyl-1-trimethylsilanyloxy-hex-4-enyl)-3-methoxy-5-methyl-4-trimethylsilanyloxy-benzyl]-dimethyl-amine 
• 116733-79-0 4-Dimethylaminomethyl-3-(1,5-dimethyl-hex-4-enyl)-2-methoxy-6-methyl-phenol 
• 100761-40-8 (+/-)-2-(1,5-dimethyl-4-hexenyl)-3-methoxy-5-methyl-2,5-cyclohexadiene-1,4-dione <(+/-)-O-methylperezone> 
• 115320-05-3 3-(2-hydroxy-6-methyl-5-hepten-2-yl)-2-methoxy-6-methyl-1,4-benzoquinone 
• 1027367-73-2 4-Dimethylaminomethyl-3-((E)-3-hydroxy-3,7-dimethyl-octa-1,6-dienyl)-2-methoxy-6-methyl-phenol 
• 127757-19-1 3-(3'-hydroxy-3'-methylbutenyl)-2-methoxy-4-<(dimethylamino)methyl>-6-methylphenol 
• 127785-63-1 2-methoxy-3-(3'-methyl-2'-butenyl)-4-<(dimethylamino)methyl>-6-methylphenol 
• 92367-72-1 (3,4-dimethoxy-5-methylphenyl)acetonitrile 
• 145263-48-5 (E)-4-(6-Dimethylaminomethyl-3-hydroxy-2-methoxy-4-methyl-phenyl)-but-3-en-2-one 
• 611-68-7 2-methoxy-6-methyl-1,4-benzoquinone 
• 104113-85-1 (4-Hydroxy-3-methoxy-5-methyl-phenyl)-acetonitrile 
• 115320-00-8 6-<(dimethylamino)methyl>-3-hydroxy-2-methoxy-4,α-dimethyl-α-(4-methyl-3-penten-1-yl)benzyl alcohol 
• 115319-98-7 4-<(dimethylamino)methyl>-2-methoxy-6-methyl-3-(methylthio)phenol 

Relevant articles and documents

Metalation of Phenols. Synthesis of Benzoquinones by the Oxidative Degradation Approach

In a effort to explore the potential of so-called oxidative degradation approach for the synthesis of quinones, we have investigated the direct metalation of a number of simple phenols such as o- and p-hydroxybenzyl alcohols, benzyl methyl ethers and N,N-dimethylbenzylamines.Apparently, only those phenolic substrates having available both a coordinating group for chelation and an electron-withdrawing group in a 1,3-relationship are efficiently lithiated, by the action of n-BuLi, in a regioselective manner.Those positions on the aromatic nucleus just flanked by a coordinating, or an acid-base, group could be metalated by action of the t-BuLi/THP system, in favorable cases.