1049038-15-4Relevant articles and documents
Catalytic C-H amination for the preparation of substituted 1,2-diamines
Olson, David E.,Du Bois
supporting information; experimental part, p. 11248 - 11249 (2009/02/05)
Rhodium-catalyzed C-H insertion of hydroxylamine-derived sulfamate esters makes possible the synthesis of unique oxathiadiazinane heterocycles, which upon mild reduction furnish differentially substituted 1,2-diamine products. This highly chemo- and diastereoselective transformation underscores the power of catalytic C-H functionalization as a general approach to C-N bond construction. Copyright
