105361-41-9Relevant articles and documents
A NOVEL RETRO-ENE REACTION THE FRAGMENTATION OF N-BENZYL-2-BENZOYL-2-METHYLPROPANIMINE
Armesto, Diego,Ramos, Ana,Perez-Ossorio, Rafael
, p. 5195 - 5198 (1982)
N-benzyl-2-benzoyl-2-methylpropanimine treated with nucleophiles undergoes a fragmentation reaction that can be envisaged as a retro-ene reaction via the formation of an intermediate hemiketal.
Photochemical Reactivity of Aldimines from 2,2-Dimethyl-3-oxo-3-phenylpropanal
Armesto, Diego,Ramos, Ana,Perez-Ossorio, Rafael,Horspool, William M.
, p. 91 - 94 (2007/10/02)
The syntheses of some thermally labile aldimines of 2,2-dimethyl-3-oxo-3-phenylpropanal are described.The aldimines (7a-c) are photochemically reactive and undergo fission mainly into isopropyl phenyl ketone.Several other minor products are also formed.On