105456-83-5Relevant articles and documents
Synthesis of Cycloalkenones via the Intramolecular Cyclopropanation of Furanyl Diazo Ketones
Padwa, Albert,Wisnieff, Thomas J.,Walsh, Edward J.
, p. 5036 - 5038 (1986)
The reaction of α-diazo ketones derived from furanyl and benzofuranyl propionic acids with rhodium(II) acetate leads to cycloalkenones in high yield.Mechanistically,, the reaction involves addition of the keto carbene to the furanyl ?-bond followed by ele