105510-24-5

Basic information

• Product Name: 2-methoxyphenyl 2-methylphenyl sulfide
• Synonyms: 2-methoxyphenyl 2-methylphenyl sulfide
• CAS NO: 105510-24-5
• Molecular Weight: 230.331
• Mol File: 105510-24-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-methoxyphenyl 2-methylphenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methoxyphenyl 2-methylphenyl sulfide(105510-24-5)
• EPA Substance Registry System: 2-methoxyphenyl 2-methylphenyl sulfide(105510-24-5)

Safety Data

• Hazardous Substances Data: 105510-24-5(Hazardous Substances Data)

Upstream product

• 529-28-2 4-iodoanisol 
• 137-06-4 2-thiocresol 
• 615-37-2 ortho-methylphenyl iodide 
• 578-57-4 2-bromoanisole 

Downstream Products

• 87524-55-8 2-(toluene-2-sulfonyl)-phenol 
• 105510-25-6 1-methoxy-2-(toluene-2-sulfonyl)-benzene 

Relevant articles and documents

Palladium-Catalyzed Enantioselective C?H Olefination of Diaryl Sulfoxides through Parallel Kinetic Resolution and Desymmetrization

The first example of PdII-catalyzed enantioselective C?H olefination with non-chiral or racemic sulfoxides as directing groups was developed. A variety of chiral diaryl sulfoxides were synthesized with high enantioselectivity (up to 99 %) throu

2-(1-benzotriazolyl)pyridine: A robust bidentate ligand for the palladium-catalyzed C-C (Suzuki, Heck, Fujiwara-Moritani, Sonogashira), C-N and C-S coupling reactions

A new class of bidentate ligand, 1-(pyridine-2-yl)-1H-benzo[d][1,2,3] triazole has been designed and employed for the palladium-catalyzed C-C (Suzuki, Heck, Fujiwara-Moritani, and Sonogashira), C-N and C-S coupling reactions. The ligand was found to be inexpensive, thermally stable, easy to synthesize from easily accessible starting materials on a multigram scale, show simplicity in use, and robustness in application, making this ligand effective for different coupling reactions. Suitably, the donor ability of the N=N bond of the benzotriazole ring and lone pair of electrons on the N of the pyridine ring enhance the bidentate ability of the ligand.

Facile preparation of aryl sulfides using palladium catalysis under mild conditions

A convenient method for C-S cross-coupling of aryl bromides with various thiols has been developed that involves the use of a 1,1′- bis(diphenylphosphino)ferrocene (DPPF)-ligated palladium complex with N,N-diisopropylethylamine (DIPEA) as the base. This coupling is tolerant of a wide range of functional groups, including hydroxy, amino, cyano, nitro, formyl, and carboxyl groups. Georg Thieme Verlag Stuttgart - New York.