105591-47-7

Basic information

• Product Name: 3-(3-CHLORO-6-METHOXYPHENYL)-1-PROPENE
• Synonyms: 3-(3-CHLORO-6-METHOXYPHENYL)-1-PROPENE;3-(5-CHLORO-2-METHOXYPHENYL)-1-PROPENE
• CAS NO: 105591-47-7
• Molecular Formula: C₁₀H₁₁ClO
• Molecular Weight: 182.65
• Mol File: 105591-47-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 233.1°C at 760 mmHg
• Flash Point: 99.6°C
• Appearance: /
• Density: 1.075g/cm³
• Vapor Pressure: 0.0868mmHg at 25°C
• Refractive Index: 1.521
• CAS DataBase Reference: 3-(3-CHLORO-6-METHOXYPHENYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(3-CHLORO-6-METHOXYPHENYL)-1-PROPENE(105591-47-7)
• EPA Substance Registry System: 3-(3-CHLORO-6-METHOXYPHENYL)-1-PROPENE(105591-47-7)

Safety Data

• Hazardous Substances Data: 105591-47-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H11ClO/c1-3-4-8-7-9(11)5-6-10(8)12-2/h3,5-7H,1,4H2,2H3

Upstream product

• 77-78-1 dimethyl sulfate 
• 13997-73-4 2-allyl-4-chlorophenol 
• 74-88-4 methyl iodide 
• 60633-25-2 2-bromo-4-chloroanisole 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 695-96-5 2-bromo-4-chlorophenol 
• 106-95-6 allyl bromide 

Downstream Products

• 105591-48-8 1-(2'-Bromopropyl)-5-chloro-2-methoxybenzene 

Relevant articles and documents

Synthesis of Self-Healing Polymers by Scandium-Catalyzed Copolymerization of Ethylene and Anisylpropylenes

Self-healing materials are of fundamental interest and practical importance. Herein we report the synthesis of a new class of self-healing materials, formed by the copolymerization of ethylene and anisyl-substituted propylenes using a sterically demanding half-sandwich scandium catalyst. The copolymerization proceeded in a controlled fashion, affording unique multi-block copolymers composed of relatively long alternating ethylene-alt-anisylpropylene sequences and short ethylene-ethylene units. By controlling the molecular weight and varying the anisyl substituents, a series of copolymers that show a wide range of glass-transition temperatures (Tg) and mechanical properties have been obtained. The copolymers with Tg below room temperature showed high elastic modulus, high toughness, and remarkable self-healability, being able to autonomously self-heal upon mechanical damage not only in a dry environment but also in water and aqueous acid and alkaline solutions, while those with Tg around or above room temperature exhibited excellent shape-memory property. The unique mechanical properties may be ascribed to the phase separation of the crystalline ethylene-ethylene nanodomains from the ethylene-alt-anisylpropylene matrix.

Selective Demethylative Cyclisation of 2-Methoxy-allylbenzenes

Treatment of 3-substituted 2-methoxyallylbenzenes with dry HBr in CHCl3 causes selective demethylative cyclisation to give 7-substituted 2-methyl-2,3-dihydrobenzofurans.The reaction involves mutual participation of allyl and 2-methoxyl groups and is sterically accelerated by substituents vicinal to OCH3.The reaction does not take place in high dielectric solvents such as DMF or DMSO.A propable mechanism envisaging a non-classical ionic transition state is proposed and the synthetic utility of this reaction is also demonstrated.