10568-20-4

Basic information

• Product Name: tert-butyl 2-iodobenzoperoxoate
• Synonyms: tert-butyl 2-iodobenzoperoxoate
• CAS NO: 10568-20-4
• Molecular Weight: 320.127
• Mol File: 10568-20-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: tert-butyl 2-iodobenzoperoxoate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 2-iodobenzoperoxoate(10568-20-4)
• EPA Substance Registry System: tert-butyl 2-iodobenzoperoxoate(10568-20-4)

Safety Data

• Hazardous Substances Data: 10568-20-4(Hazardous Substances Data)

Upstream product

• 75-91-2 tert.-butylhydroperoxide 
• 609-67-6 2-Iodobenzoyl chloride 
• 88-67-5 2-Iodobenzoic acid 

Relevant articles and documents

Synthesis of new alkenyl iodobenzoate derivatives via Kharasch-Sosnovsky reaction using tert-butyl iodo benzoperoxoate and copper (I) iodide

Abstract: The synthesis of new alkenyl iodobenzoate derivatives as allylic esters was investigated via the reaction of tert-butyl iodobenzoperoxoate with alkenes in the presence of copper salts. The best result was obtained using tert-butyl-iodobenzoperoxoate in the presence of copper (I) iodide (5?mol%) in refluxing acetonitrile with good yield (92%) in 32?h. The structure of peresters and alkenyl iodobenzoate derivatives were characterized on the basis of their FT-IR, 1HNMR, 13CNMR, and Mass spectra. Graphic abstract: The preparation of new iodo-allylic esters from alkenes in the presence of copper salts in good to excellent yields is reported in this article.[Figure not available: see fulltext.]

Asymmetric allylic oxidation with biarylbisoxazoline-copper(I) catalysis

Eight new bi-o-tolyl bisoxazolines were made and used as ligands in the copper catalyzed asymmetric allylic oxidation reaction. Three benzoyl tert-butyl peresters, p-nitro, o-iodo, and 2,4,6-trichloro were made and used with cyclohexene and cyclopentene w