1057672-67-9Relevant articles and documents
Fluorous synthesis of allylic fluorides: C-F bond formation as the detagging process
Boldon, Sophie,Moore, Jane E.,Gouverneur, Veronique
, p. 3622 - 3624 (2008)
A novel fluorous tagging-detagging strategy has been developed featuring a fluorination as the detagging process; fluorous allylsilanes were prepared by cross-metathesis and subsequently subjected to electrophilic fluorodesilylation; Selectfluor was used as the detagging reagent; the resulting allylic fluorides were successfully purified by fluorous solid phase extraction. The Royal Society of Chemistry.