10577-44-3

Basic information

• Product Name: Benzene, 1-methoxy-2-(1-propenyl)-
• CAS NO: 10577-44-3
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 10577-44-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-2-(1-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-2-(1-propenyl)-(10577-44-3)
• EPA Substance Registry System: Benzene, 1-methoxy-2-(1-propenyl)-(10577-44-3)

Safety Data

• Hazardous Substances Data: 10577-44-3(Hazardous Substances Data)

Upstream product

• 3698-28-0 2-allylanisole 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 135-02-4 ortho-anisaldehyde 
• 60604-09-3 3-phenylpropane-3,3-d₂ 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 578-57-4 2-bromoanisole 
• 107-05-1 3-chloroprop-1-ene 
• 106-95-6 allyl bromide 
• 4873-09-0 allyl tosylate 
• 18146-00-4 allyloxytrimethylsilane 
• 3066-75-9 allyl diethyl phosphate 
• 31456-98-1 methyl 3-allyl-salicylate 
• 1745-81-9 o-Allylphenol 
• 90-02-8 salicylaldehyde 

Downstream Products

• 861298-43-3 1-(2-bromo-1-methoxy-propyl)-2-methoxy-benzene 
• 2077-36-3 (E)-1-(2-methoxyphenyl)prop-1-ene 
• 93108-08-8 methyl 4-(2'-methoxyphenyl)butanoate 

Relevant articles and documents

Iron Catalyzed Double Bond Isomerization: Evidence for an FeI/FeIII Catalytic Cycle

Iron-catalyzed isomerization of alkenes is reported using an iron(II) β-diketiminate pre-catalyst. The reaction proceeds with a catalytic amount of a hydride source, such as pinacol borane (HBpin) or ammonia borane (H3N?BH3). Reactivity with both allyl arenes and aliphatic alkenes has been studied. The catalytic mechanism was investigated by a variety of means, including deuteration studies, Density Functional Theory (DFT) and Electron Paramagnetic Resonance (EPR) spectroscopy. The data obtained support a pre-catalyst activation step that gives access to an η2-coordinated alkene FeI complex, followed by oxidative addition of the alkene to give an FeIII intermediate, which then undergoes reductive elimination to allow release of the isomerization product.

Preferential Photoreaction in a Porous Crystal, Metal-Macrocycle Framework: PdII-Mediated Olefin Migration over [2+2] Cycloaddition

A nanosized confined space with well-defined functional surfaces has great potential to control the efficiency and selectivity of catalytic reactions. Herein we report that a 1,6-diene, which normally forms an intramolecular [2+2] cycloadduct under photoirradiation, preferentially undergoes a photoinduced olefin migration in a porous crystal, metal-macrocycle framework (MMF), and alternatively [2+2] cycloaddition is completely inhibited in the confined space. A plausible reaction mechanism for olefin migration triggered by the photoinduced dissociation of the Pd-Cl bond is suggested based on UV-vis diffuse reflectance spectroscopy, single-crystal XRD, and MS-CASPT2 calculation. The substrate scope of the photoinduced olefin migration in MMF was also examined using substituted allylbenzene derivatives.

Practical iron-catalyzed allylations of aryl grignard reagents

An operationally simple iron-catalyzed reductive cross-coupling reaction between aryl halides and allyl electrophiles has been developed. The underlying domino process exhibits high versatility with respect to the allylic leaving group (acetate, tosylate, diethyl phosphate, methyl carbonate, trimethylsilanolate, methanethiolate, chloride, bromide) and high economic and environmental sustainability with respect to the catalyst system (0.2-5 mol% tris(acetylacetonato)iron(III), ligand-free) and reaction conditions (tetrahydrofuran, 0°C, 45 min).