106477-02-5

Basic information

• Product Name: Peroxide, 1,1-dimethylethyl 1,2,3,4-tetrahydro-1-naphthalenyl
• CAS NO: 106477-02-5
• Molecular Formula: C14H20O2
• Molecular Weight: 220.312
• Mol File: 106477-02-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Peroxide, 1,1-dimethylethyl 1,2,3,4-tetrahydro-1-naphthalenyl(CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide, 1,1-dimethylethyl 1,2,3,4-tetrahydro-1-naphthalenyl(106477-02-5)
• EPA Substance Registry System: Peroxide, 1,1-dimethylethyl 1,2,3,4-tetrahydro-1-naphthalenyl(106477-02-5)

Safety Data

• Hazardous Substances Data: 106477-02-5(Hazardous Substances Data)

Upstream product

• 75-91-2 tert.-butylhydroperoxide 
• 119-64-2 tetralin 

Downstream Products

• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 

Relevant articles and documents

Copper catalyzed oxidation of tetralin to 1-(tert-butylperoxy)-tetralin by aqueous tert-butylhydroperoxide under phase transfer conditions

Selective α-peroxidation of tetralin by TBHP is catalyzed by copper salts with the aid of quaternary ammonium compounds in an aqueous-organic biphasic system.

Rh2(esp)2-catalyzed allylic and benzylic oxidations

The dirhodium(ii) catalyst Rh2(esp)2 allows direct solvent-free allylic and benzylic oxidations by T-HYDRO with a remarkably low catalyst loading. This method is operationally simple and scalable at ambient temperature without the use of any additives. The high catalyst stability in these reactions may be attributed to a dirhodium(ii,ii) catalyst resting state, which is less prone to decomposition.

Synthesis, single crystal structures and efficient catalysis for tetralin oxidation of two novel complexes of Cu(II) with 2-aminomethyl pyridine

Two novel Cu(II) complexes were synthesized through the reaction of 2-aminomethyl pyridine (AMP) with CuCl2·2H2O by changing the metal/ligand ratio. Their structures were thoroughly characterized by FT-IR, elemental analysis and X-ray diffraction method. The results revealed that complex 1 [Cu(AMP)Cl2] consists of isolated binuclear molecules unit and displays distorted tetragonal pyramid. Complex 2 [Cu(AMP) 2(H2O)2]Cl2 exhibits a octahedral geometry. The complexes were both evaluated as catalysts in the tetralin oxidation with TBHP as oxidant. Complex 1 showed high catalytic activity and selectivity towards α-tetralone under mild conditions. Thus, under the optimized conditions (acetonitrile 10 ml, catalyst 0.045 mmol, tetralin 4.5 mmol, 65% TBHP 22.5 mmol, T = 50 °C), the conversion of tetralin reached 89% with a selectivity of 71% towards α-tetralone. Compared with complex 1, complex 2 displayed low catalytic activity mainly due to the strong steric hindrance from the two coordinated 2-aminomethyl pyridine molecules.