106484-47-3

Basic information

• Product Name: oxa<2.2>metacyclophane
• CAS NO: 106484-47-3
• Molecular Weight: 210.276
• Mol File: 106484-47-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: oxa<2.2>metacyclophane(CAS DataBase Reference)
• NIST Chemistry Reference: oxa<2.2>metacyclophane(106484-47-3)
• EPA Substance Registry System: oxa<2.2>metacyclophane(106484-47-3)

Safety Data

• Hazardous Substances Data: 106484-47-3(Hazardous Substances Data)

Upstream product

• 620-24-6 3-Hydroxybenzyl alcohol 
• 74597-04-9 m-hydroxybenzyl bromide 
• 76106-64-4 m-hydroxytoluene-α-thiol 
• 117144-70-4 10-oxa-2-thia<3.2>metacyclophane 

Relevant articles and documents

Thia- and Oxa-metacyclophanes: Synthesis, Helicity, and Stereoselective Formation of Sulphoxides

The helical structures of the new highly strained -metacyclophanes (5) (the structure of which has been determined by X-ray crystallography) and (8) have been studied and the four stereoisomeric sulphoxides (6) obtained from (5) have been separated by h.p.l.c.; the diastereomeric excess in the oxidation of the helical sulphide (5) to yield the sulphoxides (6) is 91 percent.