106729-73-1

Basic information

• Product Name: cyclohex-2-enyl-N-benzoylbenzimidate
• CAS NO: 106729-73-1
• Molecular Weight: 305.376
• Mol File: 106729-73-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cyclohex-2-enyl-N-benzoylbenzimidate(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohex-2-enyl-N-benzoylbenzimidate(106729-73-1)
• EPA Substance Registry System: cyclohex-2-enyl-N-benzoylbenzimidate(106729-73-1)

Safety Data

• Hazardous Substances Data: 106729-73-1(Hazardous Substances Data)

Upstream product

• 3413-44-3 (R)-2-cyclohexen-1-ol 
• 614-28-8 N-benzoylbenzamide 
• 614-28-8 dibenzoylimide 
• 822-67-3 Cyclohex-2-enol 

Downstream Products

• 5456-63-3 trans-2-hydroxycyclohexylamine hydrochloride 
• 57707-58-1 cis-2-benzamidocyclohexyl benzoate 
• 5450-83-9 N-(cis-2-hydroxycyclohexyl)benzamide 
• 116429-75-5 1,2-cis-2,3-trans-2-benzamido-3-iodocyclohexyl benzoate 
• 106729-74-2 1,2-cis-2,3-trans-2-benzamido-3-bromocyclohexyl benzoate 
• 116429-76-6 ((3aS,4S,7aS)-4-Bromo-2-ethoxy-2-phenyl-hexahydro-benzooxazol-3-yl)-phenyl-methanone 

Relevant articles and documents

SYNTHESIS OF (L)-DAUNOSAMINE AND RELATED AMINO SUGARS

1-(2-Furyl)ethanol (6) has been converted into methyl (+/-)-daunosaminide (1) and methyl (+/-)-ristosaminide (3) by use of an intramolecular cyclisation of a trichloroacetimidate group. (+/-)-Daunosamine (1) has been obtained more directly from the alcohol (10) by use of a modified Mitsunobu reaction; the scope of the latter reaction has been explored using cyclohex-2-en-1-ol as a model substrate.Asymmetric reduction of 2-acetylfuran (5) has given (S)-1-(2-furyl)ethanol (46) in good enantiomeric excess, thus providing a short route to the L-enantiomers of the amino sugars (1), (2), and (3) from a cheap, non-carbohydrate precursor.