107222-71-9Relevant articles and documents
Unusual Reaction to Glycosyl Urethanes During a Synthesis of Glucopeptides.
Kolar, Chenek,Knoedler, Ursula,Seiler, Fritz R.,Fehlhaber, Hans-Wolfram,Sinnwell, Volker,et al.
, p. 577 - 582 (2007/10/02)
Reaction of the disaccharide halide 1 with N-(3,5-dimethoxy-α,α-dimethylbenzyloxycarbonyl)-L-serine benzyl ester (5) unexpectedly yields the glycosyl urethane 10.Glycosidation of 5 predominantly occurs at the urethane oxygen and not at the free hydroxy gr