107474-17-9

Basic information

• Product Name: Re(N-2,6-C₆H₃i-Pr₂)2(CH₂t-Bu)Cl₂
• Synonyms: Re(N-2,6-C₆H₃i-Pr₂)2(CH₂t-Bu)Cl₂
• CAS NO: 107474-17-9
• Molecular Weight: 678.803
• Mol File: 107474-17-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Re(N-2,6-C₆H₃i-Pr₂)2(CH₂t-Bu)Cl₂(CAS DataBase Reference)
• NIST Chemistry Reference: Re(N-2,6-C₆H₃i-Pr₂)2(CH₂t-Bu)Cl₂(107474-17-9)
• EPA Substance Registry System: Re(N-2,6-C₆H₃i-Pr₂)2(CH₂t-Bu)Cl₂(107474-17-9)

Safety Data

• Hazardous Substances Data: 107474-17-9(Hazardous Substances Data)

Upstream product

• 54773-23-8 dineopentylzinc 
• 56-34-8 tetraethylammonium chloride 

Downstream Products

• 118968-18-6 Re(O)(N-2,6-C₆H₃i-Pr₂)2(CH₂t-Bu) 
• 107474-18-0 Re(2,6-i-Pr₂C₆H₃N)2(CH-t-Bu)Cl 
• 153218-89-4 Re{C₆H₃(CH(CH₃)2)2(N)}2{CHCHP(CH₃)2(C₆H₅)}(CH₂C(CH₃)3) 
• 78204-84-9 1,8-diazabicyclo<5.4.0>undec-7-ene hidrochloride 

Relevant articles and documents

A high yield route to rhenium(VII) bis(imido) neopentylidene complexes

The reaction between ReO3(OSiMe3) and ArNCO (Ar = 2,6-diisopropylphenyl) yields what is believed to be a mixture of Re2Ox (NAr)7-x complexes, one of which, Re2O2(NAr)5 (1), can be isolated in ～30% yield. Pure 1, or the crude mixture, when treated with 3 equiv of py·HCl (py = pyridine) yields Re(NAr)2(Py)Cl3 (2) in 70-80% isolated yield vs. ReO3(OSiMe3). Addition of 0.65 equiv of Zn(CH2-t-Bu)2 to 2 yields Re(NAr)2(CH2-t-Bu)Cl2 (3) in 75% isolated yield. Dehydrohalogenation of 3 with DBU yields Re(NAr)2(CH-t-Bu)Cl (4) virtually quantitatively, which can be treated with LiOR (OR = OCH(C-F3)2 or O-2,6-C6H3-i-Pr2) to give relatives of the type Re-(NAr)2(CH-t-Bu)(OR) (5). Compounds 4 and 5 are very soluble, presumably monomeric, 18-electron complexes that do not react with cis-2-pentene or norbornene.