108965-84-0

Basic information

• Product Name: 2,4-Decadienoic acid, methyl ester, (Z,E)-
• Synonyms: 2,4-Decadienoic acid, methyl ester, (Z,E)-;.(2Z,4E)-methyl decadionate;.Deca-2c,4t-diensaeure-methylester;.deca-2c,4t-dienoic acid methyl ester;(2Z,4E)-methyl-decadienoate;.methyl (2Z,4E)-decadienoate;.(Z,E)-2,4-decadienoic acid,methyl ester
• CAS NO: 108965-84-0
• Molecular Formula: C11H18O2
• Molecular Weight: 182.263
• Mol File: 108965-84-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 255.67°C (rough estimate)
• Density: 0.9131
• Refractive Index: 1.4876 (estimate)
• CAS DataBase Reference: 2,4-Decadienoic acid, methyl ester, (Z,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Decadienoic acid, methyl ester, (Z,E)-(108965-84-0)
• EPA Substance Registry System: 2,4-Decadienoic acid, methyl ester, (Z,E)-(108965-84-0)

Safety Data

• Hazardous Substances Data: 108965-84-0(Hazardous Substances Data)

Upstream product

• 108965-81-7 (E)-(2S,3S)-2-Hydroxy-3-trimethylsilanyl-dec-4-enoic acid methyl ester 
• 628-71-7 1-Heptyne 
• 292638-85-8 acrylic acid methyl ester 
• 118793-68-3 methyl deca-(2Z)-en-4-ynoate 
• 6214-22-8 methyl (Z)-3-bromoacrylate 
• 7328-33-8 methyl (2E,4E)-decadienoate 
• 1360440-03-4 (+/-)-methyl 3,4-decadienoate 
• 818-72-4 1-Octyn-3-ol 

Downstream Products

• 110-42-9 Methyl decanoate 

Relevant articles and documents

Stereoselective Synthesis of (2E,4E)- and (2Z,4E)-2,4-Alkadienoates by the Ester Enolate Claisen Rearrangement of (E)-1-Alkyl-3-trimethylsilyl-2-propenyl Glycolates Followed by the Peterson Reaction

The ester enolate Claisen rearrangement of (E)-1-alkyl-3-trimethylsilyl-2-propenyl glycolates gave (E)-erythro-2-hydroxy-3-trimethylsilyl-4-alkenoates with high diastereoselectivity, which were stereoselectively converted into (2E,4E)- and (2Z,4E)-2,4-alkadienoates by the Peterson reaction.

Microwave-accelerated Ru-catalyzed hydrovinylation of alkynes and enynes: A straightforward approach toward 1,3-dienes and 1,3,5-trienes

Quick, but not dirty! Microwave heating was found to have a significant effect on the Ru-catalyzed hydrovinylations of alkynes. A broad range of different terminal alkynes were coupled to methyl acrylate within just 30min in good to excellent yields (see scheme). This new protocol was transferred to the hydrovinylation of enynes as novel coupling partners in C-H-activation chemistry giving different 1,3,5-trienes as the sole products. Copyright