111047-52-0

Basic information

• Product Name: methyl N-p-toluenesulfonyl-1-imino-1-phenylacetate
• Synonyms: methyl N-p-toluenesulfonyl-1-imino-1-phenylacetate
• CAS NO: 111047-52-0
• Molecular Weight: 317.365
• Mol File: 111047-52-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl N-p-toluenesulfonyl-1-imino-1-phenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl N-p-toluenesulfonyl-1-imino-1-phenylacetate(111047-52-0)
• EPA Substance Registry System: methyl N-p-toluenesulfonyl-1-imino-1-phenylacetate(111047-52-0)

Safety Data

• Hazardous Substances Data: 111047-52-0(Hazardous Substances Data)

Upstream product

• 85810-81-7 methyl acetyl of methyl phenylglyoxylate 
• 15206-55-0 methyl 2-oxo-2-phenylacetate 
• 70-55-3 toluene-4-sulfonamide 

Downstream Products

• 1453490-76-0 C₂₀H₂₁NO₅S 
• 111047-53-1 methyl 2-((4-methylphenyl)sulfonamido)-2-phenylacetate 
• 1449336-00-8 C₂₂H₂₃NO₆S 

Relevant articles and documents

Highly enantioselective aza-henry reaction of ketimines catalyzed by a chiral bifunctional thiourea-tertiary amine derived from quinine

We have developed a highly enantioselective aza-Henry reaction of aryl α-ketoester-derived N-Ts ketimines with a wide range of substrate scope by a simpler bifunctional thiourea-tertiary amine catalyst derived from quinine. A variety of ketimines were investigated and corresponding products were obtained in excellent yields (up to 99% yield) with excellent enatioselectivities (up to 99% ee).

Organocatalyzed formal [2 + 2] cycloaddition of ketimines with allenoates: Facile access to azetidines with a chiral tetrasubstituted carbon stereogenic center

An enantioselective organocatalyzed aza-MBH-type reaction of ketimines and allenoates has been developed. The present formal [2 + 2] cycloaddition produces highly functionalized azetidines with a chiral tetrasubstituted carbon stereogenic center in good to excellent yields and high enantioselectivities.