111349-90-7

Basic information

• Product Name: 5α,15α-{2,2'-{3,3'-(pyridine-3,5-diyl)-dipropionamido}diphenylene}-10α,20α-bis(o-pivalamidophenyl)porphyrinato chloromanganese(III)
• CAS NO: 111349-90-7
• Molecular Weight: 1118.62
• Mol File: 111349-90-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5α,15α-{2,2'-{3,3'-(pyridine-3,5-diyl)-dipropionamido}diphenylene}-10α,20α-bis(o-pivalamidophenyl)porphyrinato chloromanganese(III)(CAS DataBase Reference)
• NIST Chemistry Reference: 5α,15α-{2,2'-{3,3'-(pyridine-3,5-diyl)-dipropionamido}diphenylene}-10α,20α-bis(o-pivalamidophenyl)porphyrinato chloromanganese(III)(111349-90-7)
• EPA Substance Registry System: 5α,15α-{2,2'-{3,3'-(pyridine-3,5-diyl)-dipropionamido}diphenylene}-10α,20α-bis(o-pivalamidophenyl)porphyrinato chloromanganese(III)(111349-90-7)

Safety Data

• Hazardous Substances Data: 111349-90-7(Hazardous Substances Data)

Upstream product

• 7773-01-5 manganese(ll) chloride 

Relevant articles and documents

Proximal effect of the nitrogen ligands in the catalytic epoxidation of olefins by the NaOCl/manganese(III) porphyrin system

Using synthetic manganese porphyrin complexes with an imidazole or a pyridine ligand covalently attached to the macrocycle, we report the control of the reaction rate, product selectivity, and stereoselectivity by the axial ligand trans to the active site of the catalyst. The results clearly illustrate the proximal effect on nitrogen ligands in this cytochrome P-450 model.