1120350-07-3

Basic information

• Product Name: C₃₂H₄₉N₃
• CAS NO: 1120350-07-3
• Molecular Weight: 475.761
• Mol File: 1120350-07-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₃₂H₄₉N₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₂H₄₉N₃(1120350-07-3)
• EPA Substance Registry System: C₃₂H₄₉N₃(1120350-07-3)

Safety Data

• Hazardous Substances Data: 1120350-07-3(Hazardous Substances Data)

Upstream product

• 24886-73-5 1-Azidoadamantane 
• 2162-74-5 N,N'-bis(2,6-diisopropylphenyl)carbodiimide 
• 766-17-6 (2R,6S)-2,6-dimethylpiperidine 

Relevant articles and documents

Low-valent iron complexes stabilised by a bulky guanidinate ligand: Synthesis and reactivity studies

A toluene-capped guanidinato iron(i) complex [(Pipiso)Fe(η6-toluene)] (Pipiso≤[(DipN)2C(cis-NC5H8Me2-2,6)]-) was prepared by magnesium metal reduction of {[(Pipiso)FeII(μ-Br)]2} in toluene. The reactivity of the closely related FeI-FeI multiply bonded species, {[Fe(-Pipiso)]2} towards a range of unsaturated small molecule substrates was investigated, and found to be broadly similar to that of low-valent β-diketiminato iron complexes. That is, its reaction with CO yielded the iron(i) carbonyl complex [(Pipiso)Fe(CO)3], whereas reaction with CO2 formed the same product via an apparent reductive disproportionation of the substrate. In contrast, reaction between {[Fe(-Pipiso)]2} and CS2 led to reductive C≤S bond cleavage and the isolation of {[(Pipiso)Fe]2(-S)(-CS)}. Different reactivity was seen with AdN3 (Ad≤1-adamantyl), which was reductively coupled by the iron(i) dimer to give iron(ii) hexaazenyl complex {[(Pipiso)Fe]2(-AdN6Ad)}. CSIRO 2014.