112402-74-1Relevant articles and documents
Triorganotin(IV) Benzoates and Aminobenzoates
Sandhu, G. K.,Verma, S. P.,Moore, L. S.,Parish, R. V.
, p. 15 - 26 (2007/10/02)
Complexes of the general formula R3SnX, where X is the anion of benzoic acid, o-, m-, p-amino- or N-phenyl-o-amino-benzoic acid, have been prepared and characterised.A combination of molecular weight, infrared, 1H NMR and 119Sn Moessbauer measurements show that, the amino-nitrogen atoms are not coordinated to tin.When R= phenyl or cyclohexyl, the compounds are monomeric and four-coordinate, and when R is alkyl (Me, n-Pr, n-Bu) they are monomeric and five-coordinate, with a bidentate carboxylate in the equatorial position of a trigonal bipyramidal structure.
