112530-10-6

Basic information

• Product Name: 2-Oxazolidinone, 3-[[(1R,6R)-4,6-dimethyl-3-cyclohexen-1-yl]carbonyl]-4-(1-methylethyl)-, (4S)-
• CAS NO: 112530-10-6
• Molecular Formula: C15H23NO3
• Molecular Weight: 265.353
• Mol File: 112530-10-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Oxazolidinone, 3-[[(1R,6R)-4,6-dimethyl-3-cyclohexen-1-yl]carbonyl]-4-(1-methylethyl)-, (4S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxazolidinone, 3-[[(1R,6R)-4,6-dimethyl-3-cyclohexen-1-yl]carbonyl]-4-(1-methylethyl)-, (4S)-(112530-10-6)
• EPA Substance Registry System: 2-Oxazolidinone, 3-[[(1R,6R)-4,6-dimethyl-3-cyclohexen-1-yl]carbonyl]-4-(1-methylethyl)-, (4S)-(112530-10-6)

Safety Data

• Hazardous Substances Data: 112530-10-6(Hazardous Substances Data)

Upstream product

• 172821-14-6 trans-(4',6'-dimethylcyclohex-3'-ene-1'-yl)-carboxylic acid 
• 17016-83-0 (4S)-4-isopropyl-1,3-oxazolidin-2-one 
• 90719-29-2 (4S)-3-((E)-2-butenoyl)-4-(1-methylethyl)-2-oxazolidinone 
• 78-79-5 isoprene 

Relevant articles and documents

SuperQuat 5,5-dimethyl-4-iso-propyloxazolidin-2-one as a mimic of Evans 4-tert-butyloxazolidin-2-one

The incorporation of a gem-dimethyl group at the 5-position of a chiral oxazolidinone biases the conformation of the adjacent C(4)-stereodirecting group such that the gem-dimethyl-4-iso-propyl combination mimics a C(4)-tert-butyl group, providing higher levels of stereocontrol than a simple 4-iso-propyloxazolidinone. The generality of this principle is demonstrated with applications in stereoselective enolate alkylations, kinetic resolutions, Diels-Alder cycloadditions and Pd-catalysed asymmetric acetalisation reactions. The Royal Society of Chemistry 2006.

?-Solvatation von aromatischen Ringen im Uebergangszustand - ein elektronischer Beitrag zur Diastereoselektivitaet von Diels-Alder-Reaktionen

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