113008-27-8

Basic information

• Product Name: {gold(II)((CH₂)2PPh₂)NO₂}2
• CAS NO: 113008-27-8
• Molecular Weight: 912.422
• Mol File: 113008-27-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {gold(II)((CH₂)2PPh₂)NO₂}2(CAS DataBase Reference)
• NIST Chemistry Reference: {gold(II)((CH₂)2PPh₂)NO₂}2(113008-27-8)
• EPA Substance Registry System: {gold(II)((CH₂)2PPh₂)NO₂}2(113008-27-8)

Safety Data

• Hazardous Substances Data: 113008-27-8(Hazardous Substances Data)

Upstream product

• 108-03-2 1-Nitropropane 
• 79-46-9 2-nitropropane 
• 75-52-5 nitromethane 
• 99-99-0 1-methyl-4-nitrobenzene 
• 79-24-3 Nitroethane 

Relevant articles and documents

Oxidative addition of nitroalkanes to dinuclear gold(I) ylide complexes. The characterization by X-ray crystallography of Au2(ylide)2(NO2)2, a nitro complex of gold(II)

The AuI ylide complex [Au((CH2)2PPh2)]2 (1) reacts oxidatively with nitroalkanes to form a AuII product, [Au((CH2)2PPh2)NO2]2 (2-NO2). This complex was characterized by IR, NMR, and X-ray crystallography. The identity of the product was confirmed by the quantitative formation of 2-NO2 from 1 and N2O4 brown gas . The product crystallizes in a monoclinic system C2/c: a = 12.159 (2) ?, b = 14.638 (2) ?, c = 16.536 (2) ?, β = 103.757 (11)°, and Z = 4 with R = 0.036 and Rw = 0.033.