113344-30-2Relevant articles and documents
Photolysis of 3-bromochroman-4-ones
Consuelo Jiménez,Miranda, Miguel A.,Tormos, Rosa
, p. 339 - 347 (2007/10/03)
Photolysis of 3-bromochroman-4-ones (1a-f) leads to debrominated chromanones (2a-f) and chromones (3a-f) as major products. Their formation is accounted for in terms of primary cleavage of the carbon halogen bond to give α-carbonyl radicals (I) and/or cations (II). In the case of the 2,2-disubstituted compounds (1d-f), intermediates (II) undergo rearrangement with 1,2-shift of the phenyl or benzyl substituent prior to deprotonation. Minor by-products are the pentacyclic pyrone (4e) or 2-methylchromone (3a) (starting from 1e and 1f, respectively).
A NOVEL PHOTOCHEMICAL 1,4-ACYL MIGRATION IN ENOL ESTERS. THE PHOTOLYSIS OF ENOL ACETATES OF 3-PHENYLPROPIOPHENONES
Alvaro, M.,Baldovi, V.,Garcia, H.,Miranda, M. A.,Primo, J.
, p. 3613 - 3614 (2007/10/02)
Photolysis of the enol acetates 1a, b gives the 1,4-diketones 4a, b by a mechanism involving a primary homolytic carbonyl-oxygen bond cleavage, followed by 1,2-hydrogen shift and in cage recombination.