113351-26-1Relevant articles and documents
Palladium-Catalyzed Reactions of Alkenyloxiranes with Carbon Monoxide
Shimizu, Isao,Maruyama, Takashi,Makuta, Toshiyuki,Yamamoto, Akio
, p. 2135 - 2138 (1993)
Reaction of alkenyloxiranes with carbon monoxide in the presence of palladium catalysts gives unsaturated esters, β-lactones, dienes, and allylic alcohols.The selectivity of the reaction depends on the nature of the alkenyloxiranes.Carbonylation products were obtained in the reaction of terminal alkenyloxiranes and alkenyloxiranes having electron-donating substituents, whereas carbonylation scarcely took place in the reaction of alkenyloxiranes having electron-withdrawing groups; dienes and allylic alcohols were produced instead of carbonylation products.