113351-67-0

Basic information

• Product Name: (R)-N-<(S)-2-hydroxy-1-methylethyl>mandelamide
• CAS NO: 113351-67-0
• Molecular Weight: 209.245
• Mol File: 113351-67-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-N-<(S)-2-hydroxy-1-methylethyl>mandelamide(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-N-<(S)-2-hydroxy-1-methylethyl>mandelamide(113351-67-0)
• EPA Substance Registry System: (R)-N-<(S)-2-hydroxy-1-methylethyl>mandelamide(113351-67-0)

Safety Data

• Hazardous Substances Data: 113351-67-0(Hazardous Substances Data)

Upstream product

• 25726-04-9 phenylglyoxylyl chloride 
• 2749-11-3 (S)-Alaninol 
• 20698-91-3 (R)-methyl mandelate 
• 611-71-2 (R)-Mandelic Acid 
• 113336-45-1 N-(2-hydroxy-1-methylethyl)benzoylformamide 

Relevant articles and documents

Lithium Aluminium Hydride Reduction of Chiral Benzoylformamides Derived from Chiral Amino Alcohols

The reduction of benzoylformamides derived from various N- and O-substituted (S)-amino alcohols using lithium aluminium hydride was carried out.Diastereoisomeric excesses could be determined by chromatographic separation of the resulting diastereoisomeric mandelamides.In all cases, the (S,S)-diastereoisomer was obtained as the major product (1-72percent d.e.), and the degree of asymmetric induction depended largely on the N- and O-substituents of the amino alcohol moiety.A d.e. of up to 72percent was obtained for the benzoylformamide (4) derived from N-methylvalinol.