1135-34-8

Basic information

• Product Name: Benzenamine, N-(phenylmethylene)-, hydrochloride
• CAS NO: 1135-34-8
• Molecular Formula: C13H11N.ClH
• Molecular Weight: 217.698
• Mol File: 1135-34-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(phenylmethylene)-, hydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(phenylmethylene)-, hydrochloride(1135-34-8)
• EPA Substance Registry System: Benzenamine, N-(phenylmethylene)-, hydrochloride(1135-34-8)

Safety Data

• Hazardous Substances Data: 1135-34-8(Hazardous Substances Data)

Upstream product

• 538-51-2 benzylidene phenylamine 
• 612-98-6 N-benzyl-N-phenylnitrous amide 

Downstream Products

• 40251-04-5 dichloro bis(N-benzylideneaniline) palladium (II) 
• 100-52-7 benzaldehyde 
• 106-47-8 4-chloro-aniline 
• 62-53-3 aniline 
• 54873-11-9 chromium (trans-C6H5CHCH)methoxycarbene pentacarbonyl complex 
• 538-51-2 benzylidene phenylamine 
• 142-04-1 aniline hydrochloride 

Relevant articles and documents

Electrochemical Synthesis of Hindered Primary and Secondary Amines via Proton-Coupled Electron Transfer

Accessing hindered amines, particularly primary amines α to a fully substituted carbon center, is synthetically challenging. We report an electrochemical method to access such hindered amines starting from benchtop-stable iminium salts and cyanoheteroarenes. A wide variety of substituted heterocycles (pyridine, pyrimidine, pyrazine, purine, azaindole) can be utilized in the cross-coupling reaction, including those substituted with a halide, trifluoromethyl, ester, amide, or ether group, a heterocycle, or an unprotected alcohol or alkyne. Mechanistic insight based on DFT data, as well as cyclic voltammetry and NMR spectroscopy, suggests that a proton-coupled electron-transfer mechanism is operational as part of a hetero-biradical cross-coupling of α-amino radicals and radicals derived from cyanoheteroarenes.