113711-63-0Relevant articles and documents
ULTRASOUND IN ORGANIC SYNTHESIS 11.RETENTION OF OPTICAL ACTIVITY IN BARBIER REACTIONS FROM S(+) 2-OCTYL HALIDES. MECHANISTIC CONSEQUENCES
Souza-Barboza, Jayne C. de,Luche, Jean-Louis,Petrier, Christian
, p. 2013 - 2016 (1987)
S(+) 2-octyl halides react spontaneously or under sonication with lithium and cyclohexanone to give an optically active alcohol.Its enantiomeric excess and absolute configuration, strongly suggest the existence of 2 reactive intermediates following different stereochemical pathway to the condensation alcohol.