114095-82-8

Basic information

• Product Name: dicarbonyl(cyclopentadienyl)phenylthiomanganese
• Synonyms: dicarbonyl(cyclopentadienyl)phenylthiomanganese
• CAS NO: 114095-82-8
• Molecular Weight: 285.225
• Mol File: 114095-82-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: dicarbonyl(cyclopentadienyl)phenylthiomanganese(CAS DataBase Reference)
• NIST Chemistry Reference: dicarbonyl(cyclopentadienyl)phenylthiomanganese(114095-82-8)
• EPA Substance Registry System: dicarbonyl(cyclopentadienyl)phenylthiomanganese(114095-82-8)

Safety Data

• Hazardous Substances Data: 114095-82-8(Hazardous Substances Data)

Upstream product

• 12079-65-1 cymantrene 
• 1095-04-1 triphenyl thiophosphite 
• 108-98-5 thiophenol 
• 266692-52-8 dicarbonyl(cyclopentadienyl)(S-phenyl diphenylphosphinothioite)manganese 
• 40674-64-4 dicarbonyl(cyclopentadienyl)(diethylsulfide)manganese 

Downstream Products

• 114095-84-0 ((C₅H₅)(CO)2Mn)2S(C₆H₅)⁽¹⁺⁾*PF₆^(1-)=((C₅H₅)(CO)2Mn)2S(C₆H₅)(PF₆) 
• 12079-65-1 cymantrene 

Relevant articles and documents

Synthese of Cp(CO)2MnTCNE aus n (X = S, Se, Te; n = 1, 2); Festkoerperstruktur und Magnetismus

Cp(CO)2MnTCNE (1) which was first reported by M.Herberhold et al., has been obtained from the reaction of n (X = S, n = 1; X = Se, Te, n = 2) with TCNE.The synthesis of the relevant organometallic sulfur, selenium and tellurium derivatives is described.An X-ray diffraction study of the TCNE compound reveals that two Cp(CO)2MnNC-C(CN)C(CN)2 (1) molecules form centrosymmetric dimers containing a coordinated centrosymmetric (TCNE)2x- pair.The bond lengths, the ν(CN) spectra and a solid state magnetism of μeff = 1.1 μB (293 K) are all consistent with this structural finding.

A new synthesis of sulfur-containing paramagnetic manganese complexes

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