114235-33-5

Basic information

• Product Name: N-(p-chlorosulfonylphenyl)-3,4,5,6-tetrachloro-8,8-dimethoxybicyclo<2.2.1>hept-4-eno succinimide
• Synonyms: N-(p-chlorosulfonylphenyl)-3,4,5,6-tetrachloro-8,8-dimethoxybicyclo<2.2.1>hept-4-eno succinimide
• CAS NO: 114235-33-5
• Molecular Weight: 535.616
• Mol File: 114235-33-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(p-chlorosulfonylphenyl)-3,4,5,6-tetrachloro-8,8-dimethoxybicyclo<2.2.1>hept-4-eno succinimide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(p-chlorosulfonylphenyl)-3,4,5,6-tetrachloro-8,8-dimethoxybicyclo<2.2.1>hept-4-eno succinimide(114235-33-5)
• EPA Substance Registry System: N-(p-chlorosulfonylphenyl)-3,4,5,6-tetrachloro-8,8-dimethoxybicyclo<2.2.1>hept-4-eno succinimide(114235-33-5)

Safety Data

• Hazardous Substances Data: 114235-33-5(Hazardous Substances Data)

Upstream product

• 36898-42-7 4-(2,5-dioxo-2,5-dihydro-1H-pyrrol-1-yl)benzenesulfonyl chloride 
• 2207-27-4 5,5-dimethoxy-1,2,3,4-tetrachlorocyclopentadiene 

Downstream Products

• 114235-36-8 C₁₇H₁₅Cl₄N₃O₆S 
• 114235-35-7 N-Phenyl-4-((1S,2S,6R,7R)-1,7,8,9-tetrachloro-10,10-dimethoxy-3,5-dioxo-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-4-yl)-benzenesulfonamide 

Relevant articles and documents

DIELS-ALDER REACTIONS USING N-(p-CHLOROSULFONYLPHENYL)MALEIMIDE AS DIENOPHILE

N-(p-chlorosulfonylphenyl)maleimide reacts as a dienophile with cyclopentadiene, furan, 2,3-dimethylbutadiene, anthracene, 1,3-cyclohexadiene, 1,2,3,4-tetrachloro-5,5-dimethoxycyclopentadiene, hexachlorocyclopentadiene and tetraphenylcyclopentadienone to give the chlorosulfonyl adducts (2, 10, 18, 24, 32, 40, 48, 56).These were converted into derivatives by reaction with amines, hydrazine and sodium azide.The stereochemistry of the Diels-Alder adducts was determined by NMR spectroscopy of the adducts and their dimethylamides; and the relative ease of addition is discussed.Attempted formation of (2) by chlorosulfonation of the adduct from N-phenylmaleimide and cyclopentadiene was unsuccessful.The spectral data are briefly discussed.