1147845-95-1Relevant articles and documents
Nickel- and rhodium-catalyzed addition of terminal silylacetylenes to propargyl amines: Catalyst-dependent complementary regioselectivity
Matsuyama, Naoto,Hirano, Koji,Satoh, Tetsuya,Miura, Masahiro
experimental part, p. 3576 - 3578 (2009/09/05)
The cross-addition of terminal silylacetylenes to γ-arylated propargyl amines occurs efficiently via C - H cleavage by using either a nickel or rhodium catalyst. Taking advantage of the catalyst-controlled switching of regioselectivity in the reaction, bo