1150632-93-1Relevant articles and documents
Synthesis of -CN- linked covalent organic frameworks: Via the direct condensation of acetals and amines
Li, Zhi-Jun,Ding, San-Yuan,Xue, Hua-Dong,Cao, Wei,Wang, Wei
, p. 7217 - 7220 (2016)
We demonstrate herein a facile approach for constructing -CN- linked COFs from acetals. Three new COFs (imine-linked LZU-20, hydrazone-linked LZU-21, and azine-linked LZU-22) were synthesized by the direct condensation of dimethyl acetals and amines. All
Self-assembly of a trigonal bipyramidal architecture with stabilisation of iron in three spin states
Borilovi?, Ivana,Riddell, Imogen A.,Taylor, Lauren L. K.,Tuna, Floriana,Vitorica-Yrezabal, I?igo J.
, p. 11252 - 11255 (2021/11/04)
Self-assembly and characterisation of a supramolecular trigonal bipyramidal iron cage containing an [FeIII(μ2-F)6(FeII)3]3+ star motif at its core is reported. The complex can be formed in a one step reaction using an heterotopic ligand that supports site-specific incorporation of iron in three distinct electronic configurations: low-spin FeII, high-spin FeII and high-spin FeIII, with iron(ii) tetrafluoroborate as the source of the bridging fluorides. Formation of a μ2-F bridged mixed-valence FeII-FeIII star is unprecedented. The peripheral high-spin FeII centres of the mixed-valence tetranuclear star incorporated in the iron cage are highly anisotropic and engage in F-mediated antiferromagnetic exchange with the central FeIII ion.
Fluorescent BODIPY-based Zn(II) complex as a molecular probe for selective detection of neurofibrillary tangles in the brains of Alzheimer's disease patients.
Ojida, Akio,Sakamoto, Takashi,Inoue, Masa-Aki,Fujishima, Sho-hei,Lippens, Guy,Hamachi, Itaru
supporting information; experimental part, p. 6543 - 6548 (2009/09/26)
We have developed a new fluorescent binuclear Zn(II) complex for the detection of neurofibrillary tangles (NFTs) of hyperphosphorylated tau proteins, a representative hallmark of Alzheimer's disease (AD). The probe 1 incorporates a fluorescent BODIPY unit