115146-99-1

Basic information

• Product Name: 1-methyleneundecylbenzene
• Synonyms: 1-methyleneundecylbenzene
• CAS NO: 115146-99-1
• Molecular Weight: 244.42
• Mol File: 115146-99-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-methyleneundecylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyleneundecylbenzene(115146-99-1)
• EPA Substance Registry System: 1-methyleneundecylbenzene(115146-99-1)

Safety Data

• Hazardous Substances Data: 115146-99-1(Hazardous Substances Data)

Upstream product

• 4433-30-1 1-phenylundecan-1-one 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 7534-40-9 2-phenylallyl acetate 
• 39691-62-8 nonylmagnesium bromide 
• 765-03-7 1-dodecyne 
• 104849-67-4 2-iodododect-1-ene 
• 98-80-6 phenylboronic acid 
• 98-81-7 1-bromovinylbenzene 
• 344453-19-6 n-decylzinc iodide 
• 98-86-2 acetophenone 
• 17049-50-2 n-decyl magnesium bromide 
• 2050-77-3 Iododecane 
• 151073-86-8 1-phenyl-1-ethenylzinc bromide 
• 112-29-8 1-bromo dodecane 

Downstream Products

• 2719-61-1 2-phenyldodecane 

Relevant articles and documents

A convenient hydroiodination of alkynes using I2/PPh3/H2O and its application to the one-pot synthesis of trisubstituted alkenes via iodoalkenes using Pd-catalyzed cross-coupling reactions

A facile hydroiodination of alkynes using readily-available reagents such as I2, PPh3, and H2O has been developed. This is extended to the one-pot synthesis of trisubstituted alkenes from alkynes via iodoalkenes using Pd-c

Electrochemistry enabled selective vicinal fluorosulfenylation and fluorosulfoxidation of alkenes

Both sulfur and fluorine play important roles in organic synthesis, the life science, and materials science. The direct incorporation of these elements into organic scaffolds with precise control of the oxidation states of sulfur moieties is of great significance. Herein, we report the highly selective electrochemical vicinal fluorosulfenylation and fluorosulfoxidation reactions of alkenes, which were enabled by the unique ability of electrochemistry to dial in the potentials on demand. Preliminary mechanistic investigations revealed that the fluorosulfenylation reaction proceeded through a radical-polar crossover mechanism involving a key episulfonium ion intermediate. Subsequent electrochemical oxidation of fluorosulfides to fluorosulfoxides were readily achieved under a higher applied potential with the adventitious H2O in the reaction mixture.

Highly selective reactions of unbiased alkenyl halides and alkylzinc halides: Negishi-plus couplings

High yielding stereo- and chemoselective Pd-catalyzed cross-couplings in THF at room temperature of alkenyl iodides and bromides with primary and secondary alkyl zinc iodides have been developed with the aid of N-methyimidazole as the key additive.