115289-04-8

Basic information

• Product Name: N-(2-hydroxyphenyl)methyl-bis(2-pyridylmethyl)amine
• Synonyms: N-(2-hydroxyphenyl)methyl-bis(2-pyridylmethyl)amine
• CAS NO: 115289-04-8
• Molecular Weight: 305.379
• Mol File: 115289-04-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: N-(2-hydroxyphenyl)methyl-bis(2-pyridylmethyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-hydroxyphenyl)methyl-bis(2-pyridylmethyl)amine(115289-04-8)
• EPA Substance Registry System: N-(2-hydroxyphenyl)methyl-bis(2-pyridylmethyl)amine(115289-04-8)

Safety Data

• Hazardous Substances Data: 115289-04-8(Hazardous Substances Data)

Upstream product

• 3731-51-9 2-(Aminomethyl)pyridine 
• 90-02-8 salicylaldehyde 
• 1539-42-0 bis[(2-pyridyl)methyl]amine 
• 60041-69-2 acetic acid 2,6-bis(bromomethyl)phenyl ester 
• 1539-41-9 N,N-bis<(2-pyridyl)methyl>amine trihydrochloride 
• 1121-60-4 pyridine-2-carbaldehyde 
• 444069-42-5 acetic acid 2-[(bis-pyridin-2-ylmethyl-amino)-methyl]-phenyl ester 

Downstream Products

• 1408320-36-4 2-(2-((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy)-N,N-diphenylacetamide 
• 676144-63-1 chloro-(N-(2-hydroxyphenyl)methylbis(2-pyridylmethyl)amino)copper(I) 
• 178819-35-7 [Cu(C₁₉H₁₈N₃O)(O₂CC₆H₄NO₂)] 
• 209454-10-4 Zn(C₁₉H₁₈N₃O)(4-chlorothiophenolate) 
• 209454-09-1 Zn(C₁₉H₁₈N₃O)(thiophenolate) 
• 209454-08-0 Zn(C₁₉H₁₈N₃O)(phenolate) 

Relevant articles and documents

A fluorescence turn-on H2O2 probe exhibits lysosome-localized fluorescence signals

A new fluorescence turn-on probe that responds exclusively to H 2O2 exhibits subcellular localized fluorescence staining of lysosomes.

Hydrogen evolution catalyzed by an iron polypyridyl complex in aqueous solutions

Iron complexes containing tetradentate monophenolate ligands have been found to be highly active for the electrocatalytic reduction of protons to hydrogen gas. Catalysis occurs at -1.17 V vs SCE in CH3CN with a turnover frequency of up to 1000 s-1 and a 660 mV overpotential. Interestingly, the catalyst activity is enhanced in the presence of water, achieving turnover frequencies of 3000 s-1 with an overpotential of 800 mV, making it one of the most active iron electrocatalysts currently reported. The catalyst is also capable of generating hydrogen from purely aqueous buffer solutions of pH 3-5 with Faradaic efficiencies of 98%.

Synthesis and characterization of molybdenum oxo complexes of two tripodal ligands: Reactivity studies of a functional model for molybdenum oxotransferases

Reaction of the tetradentate ligand N-(2-hydroxybenzyl)-N,N-bis(2- pyridylmethyl)amine (L-OH) with MoO2Cl2 in methanol in the presence of NaOMe and PF6- results in the formation of [MoO2(L-O)]PF6. Similarly, the reaction of N-(2-mercaptobenzyl)-N,N-bis(2-pyridylmethyl)amine (L-SH) with MoO 2(acac)2 leads to the formation of [MoO 2(L-S)]+. The dioxo-molybdenum complex [MoO 2(L-O)]+ reacts with phosphines in methanol to afford phosphine oxides and an air-sensitive molybdenum complex, tentatively identified as [Mo(IV)O(L-O)(OCH3)]. The latter complex is capable of reducing biological oxygen donors such as DMSO or nitrate, thereby mimicking the activity of DMSO reductase and nitrate reductase. Reaction of [MoO2(L-O)] PF6 with PPh3 in other solvents than methanol leads to the formation of the Mo(V) dimer [(L-O)OMo(μ-O)MoO(L-O)](PF6) 2. The crystal structures of [MoO2(L-O)]PF6 and the μ-oxo bridged dimer are presented. The Royal Society of Chemistry 2005.