116003-78-2

Basic information

• Product Name: Methyl 2-azido-2-deoxy-4,6-O-(phenylmethylene)-α-D-mannopyranoside
• Synonyms: Methyl 2-azido-2-deoxy-4,6-O-(phenylmethylene)-α-D-mannopyranoside
• CAS NO: 116003-78-2
• Molecular Weight: 307.306
• Mol File: 116003-78-2.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Methyl 2-azido-2-deoxy-4,6-O-(phenylmethylene)-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2-azido-2-deoxy-4,6-O-(phenylmethylene)-α-D-mannopyranoside(116003-78-2)
• EPA Substance Registry System: Methyl 2-azido-2-deoxy-4,6-O-(phenylmethylene)-α-D-mannopyranoside(116003-78-2)

Safety Data

• Hazardous Substances Data: 116003-78-2(Hazardous Substances Data)

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 115945-96-5 methyl 2-azido-4,6-O-benzylidene-2-deoxy-3-O-(N-imidazolylsulfonyl)-α-D-altropyranoside 
• 116003-77-1 2-azido-2-deoxy-4,6-O-(phenylmethylene)methyl-α-D-altropyranoside 
• 115945-97-6 methyl 3-O-acetyl-2-azido-4,6-O-benzylidene-2-deoxy-α-D-mannopyranoside 
• 129217-24-9 4,6-O-benzylidene-1-O-methyl-2-O-trifluoromethylsulfonate-α-D-glucopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 

Downstream Products

• 68733-20-0 1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-α-D-mannopyranoside 
• 635292-85-2 1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-β-D-mannopyranose 
• 1644625-34-2 C₂₇H₃₄N₂O₈ 
• 1644625-33-1 C₂₄H₃₆N₂O₈ 
• 1644625-32-0 C₂₁H₃₀N₂O₈ 
• 1644625-31-9 C₂₂H₃₂N₂O₈ 
• 1644625-30-8 C₂₈H₃₆N₂O₈ 
• 1644625-29-5 C₂₇H₃₄N₂O₈ 
• 1644625-28-4 C₂₅H₃₈N₂O₈ 
• 1644625-42-2 C₃₄H₃₈N₂O₈S 
• 1644625-41-1 C₃₁H₄₀N₂O₈S 
• 1644625-40-0 C₂₈H₃₄N₂O₈S 
• 1644625-39-7 C₂₉H₃₆N₂O₈S 
• 1644625-38-6 C₃₅H₄₀N₂O₈S 

Relevant articles and documents

Synthesis of 1,2,3-triazolyl analog of Neisseria meningitidis A capsular polysaccharide

Towards constructing a stable, non-hydrolyzable linkage for Neisseria meningitidis type A (MenA) polysaccharide, the phosphate bridge of its (1→6)-linked 2-acetamido-2-deoxy-α-D-mannopyranosyl phosphate repeating unit was replaced by a triazolyl analog using Cu(I) catalyzed click reaction. The synthesis involved anomeric azidation of N-acetyl-D-mannosamine derivative from its acetate precursor using stoichiometric amount of FeCl3 and one-pot synthesis of precursors for di- and tri- triazolyl saccharides with an azidoethyl spacer at the reducing end for bioconjugation.

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Versatile syntheses of C2-linked and C2-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.

Chemoenzymatic synthesis of CMP-N-acetyl-7-fluoro-7-deoxy-neuraminic acid

7-Fluoro sialic acid was prepared and activated as cytidine monophosphate (CMP) ester. The synthesis started with d-glucose, which was efficiently converted into N-acetyl-4-fluoro-4-deoxy-d-mannosamine. Aldolase catalyzed transformation yielded the corres