116611-36-0Relevant articles and documents
Bronsted acid-catalyzed decarboxylative redox amination: Formation of N-alkylindoles from azomethine ylides by isomerization
Mao, Hui,Wang, Sichang,Yu, Peng,Lv, Huiqing,Xu, Runsheng,Pan, Yuanjiang
, p. 1167 - 1169 (2011)
A Bronsted acid-catalyzed decarboxylative redox amination involving aldehydes with 2-carboxyindoline for the synthesis of N-alkylindoles is described. The decarboxylative condensations of aldehydes with 2-carboxyindoline produce azomethine ylides in situ,
THE REACTION OF SECONDARY α-AMINO ACIDS WITH CARBONYL COMPOUNDS. PROPERTIES OF THE INTERMEDIATE AZOMETHINE YLIDES. OXAZOLIDINE FORMATION VERSUS 1,4-PROTOTROPY.
Aly, Moustafa F.,Ardill, Harriet,Grigg, Ronald,Leong-Ling, Stephanie,Rajviroongit, Shuleewan,Surendrakumar, Sivagnanasundram
, p. 6077 - 6080 (2007/10/02)
Cyclic secondary α-amino acids react regiospecifically, via antidipole formation, with aldehydes bearing electron withdrawing substituents to give oxazolidines in good yield.In certain cases structural features in the α-amino acid promote a 1,4-prototropi